Sir William Robert Grove, FRS FRSE (11 July 1811 – 1 August 1896) was a Welsh judge and physical scientist. He anticipated the general theory of the conservation of energy, and was a pioneer of fuel cell technology. He invented the Grove voltaic cell.
Born in Swansea, Wales, Grove was the only child of John, a magistrate and deputy lieutenant of Glamorgan, and his wife, Anne (née Bevan).
His early education was in the hands of private tutors, before he attended Brasenose College, Oxford to study classics, though his scientific interests may have been cultivated by mathematician Baden Powell. Otherwise, his taste for science has no clear origin though his circle in Swansea was broadly educated. He graduated in 1832.
In 1835, he was called to the bar by Lincoln's Inn. In the same year, Grove joined the Royal Institution and was a founder of the Swansea Literary and Philosophical Society, an organisation with which he maintained close links.
In 1829, at the Royal Institution, Grove met Emma Maria Powles.. They married in 1837.
The couple embarked on a tour of the continent for their honeymoon. This sabbatical offered Grove an opportunity to pursue his scientific interests and resulted in his first scientific paper suggesting some novel constructions for electric cells.
During 1839, Grove developed a novel form of electric cell, the Grove cell, which used zinc and platinum electrodes exposed to two acids and separated by a porous ceramic pot. Grove announced the latter development to the Académie des Sciences in Paris in 1839. In 1840 Grove invented one of the first incandescent electric lights, which was later perfected by Thomas Edison.
Later that year, he gave another account of his development at the British Association for the Advancement of Science meeting in Birmingham, where it aroused the interest of Michael Faraday. On Faraday's invitation Grove presented his discoveries at the prestigious Royal Institution Friday Discourse on 13 March 1840.
Grove's presentation made his reputation, and he was soon proposed for Fellowship of the Royal Society by such distinguished men as William Thomas Brande, William Snow Harris and Charles Wheatstone. Grove also attracted the attention of John Peter Gassiot, a relationship that resulted in Grove's becoming the first professor of experimental philosophy at the London Institution in 1841. Grove's inaugural lecture in 1842 was the first announcement of what Grove called the correlation of physical forces, in modern terms, the conservation of energy.
In 1842, Grove developed the first fuel cell (which he called the gas voltaic battery), which produced electrical energy by combining hydrogen and oxygen, and described it using his correlation theory. In developing the cell and showing that steam could be disassociated into oxygen and hydrogen, and the process reversed, he was the first person to demonstrate the thermal dissociation of molecules into their constituent atoms. The first demonstration of this effect, he gave privately to Faraday, Gassiot and Edward William Brayley, his scientific editor.
His work also led him to early insights into the nature of ionisation. For observations made in Ref., Grove is credited for the discovery of sputtering.
In the 1840s, he collaborated with Gassiot at the London Institution on photography and the Daguerreotype and calotype processes. Inspired by his legal practice, he presciently observed:
It would be vain to attempt specifically to predict what may be the effect of Photography on future generations. A Process by which the most transient actions are rendered permanent, by which facts write their own annals in a language that can never be obsolete, forming documents which prove themselves, – must interweave itself not only with science but with history and legislature.
In 1852, he discovered striae, dark bands that occur in electrical breakdown, and investigated their character, presenting his work in an 1858 Bakerian lecture.
On the Correlation of Physical Forces
In 1846, Grove published On The Correlation of Physical Forces in which he anticipated the general theory of the conservation of energy that was more famously put forward in Hermann von Helmholtz' Über die Erhaltung der Kraft (On the Conservation of Force) published the following year. His 1846 Bakerian lecture relied heavily on his theory.
James Prescott Joule had been energized by his investigations into the mechanical equivalent of heat by comparing the mass of coal consumed in a steam engine with the mass of zinc consumed in a Grove battery in performing a common quantity of mechanical work. Grove was certainly familiar with William Thomson's theoretical analysis of Joule's experimental results and Thomson's immature suggestions of conservation of energy. Thomson's public champion, Peter Guthrie Tait was initially a supporter of Grove's ideas but later dismissed them with some coolness.
Though Groves's ideas were forerunners of the theory of the conservation of energy, they were qualitative, unlike the quantitative investigations of Joule or Julius Robert von Mayer. His ideas also shaded into broader speculation, such as the nature of Olbers's paradox, which he may have discovered for himself rather than through a direct knowledge.