James Prescott Joule (; 24 December 1818 – 11 October 1889) was an English physicist. Joule studied the nature of heat and discovered its relationship to mechanical work. This led to the law of conservation of energy, which in turn led to the development of the first law of thermodynamics. The SI unit of energy, the joule (J), is named after him.
He worked with Lord Kelvin to develop an absolute thermodynamic temperature scale, which came to be called the Kelvin scale. Joule also made observations of magnetostriction, and he found the relationship between the current through a resistor and the heat dissipated, which is also called Joule's first law. His experiments about energy transformations were first published in 1843.
James Joule was born in 1818, the son of Benjamin Joule, a wealthy brewer, and his wife, Alice Prescott, on New Bailey Street in Salford. Joule was tutored as a young man by the famous scientist John Dalton and was strongly influenced by chemist William Henry and Manchester engineers Peter Ewart and Eaton Hodgkinson. He was fascinated by electricity, and he and his brother experimented by giving electric shocks to each other and to the family's servants.
As an adult, Joule managed the brewery. Science was merely a serious hobby. Sometime around 1840, he started to investigate the feasibility of replacing the brewery's steam engines with the newly invented electric motor. His first scientific papers on the subject were contributed to William Sturgeon's Annals of Electricity. Joule was a member of the London Electrical Society, established by Sturgeon and others.
Motivated in part by a businessman's desire to quantify the economics of the choice, and in part by his scientific inquisitiveness, he set out to determine which prime mover was more efficient. He discovered Joule's first law in 1841, that "the heat which is evolved by the proper action of any voltaic current is proportional to the square of the intensity of that current, multiplied by the resistance to conduction which it experiences". He went on to realize that burning a pound of coal in a steam engine was more economical than a costly pound of zinc consumed in an electric battery. Joule captured the output of the alternative methods in terms of a common standard, the ability to raise a mass weighing one pound to a height of one foot, the foot-pound.
However, Joule's interest diverted from the narrow financial question to that of how much work could be extracted from a given source, leading him to speculate about the convertibility of energy. In 1843 he published results of experiments showing that the heating effect he had quantified in 1841 was due to generation of heat in the conductor and not its transfer from another part of the equipment. This was a direct challenge to the caloric theory which held that heat could neither be created nor destroyed. Caloric theory had dominated thinking in the science of heat since introduced by Antoine Lavoisier in 1783. Lavoisier's prestige and the practical success of Sadi Carnot's caloric theory of the heat engine since 1824 ensured that the young Joule, working outside either academia or the engineering profession, had a difficult road ahead. Supporters of the caloric theory readily pointed to the symmetry of the Peltier–Seebeck effect to claim that heat and current were convertible in an, at least approximately, reversible process.
The mechanical equivalent of heat
Further experiments and measurements with his electric motor led Joule to estimate the mechanical equivalent of heat as 4.1868 joules per calorie (work needed to raise the temperature of one gram of water by one degree Celsius or Kelvin). He announced his results at a meeting of the chemical section of the British Association for the Advancement of Science in Cork in August 1843 and was met by silence.
Joule was undaunted and started to seek a purely mechanical demonstration of the conversion of work into heat. By forcing water through a perforated cylinder, he could measure the slight viscous heating of the fluid. He obtained a mechanical equivalent of 770 foot-pounds force per British thermal unit (4.14 J/cal). The fact that the values obtained both by electrical and purely mechanical means were in agreement to at least two significant digits was, to Joule, compelling evidence of the reality of the convertibility of work into heat.
Wherever mechanical force is expended, an exact equivalent of heat is always obtained.
Joule now tried a third route. He measured the heat generated against the work done in compressing a gas. He obtained a mechanical equivalent of 798 foot-pounds force per British thermal unit (4.29 J/cal). In many ways, this experiment offered the easiest target for Joule's critics but Joule disposed of the anticipated objections by clever experimentation. Joule read his paper to the Royal Society on 20 June 1844, but his paper was rejected for publication by the Royal Society and he had to be content with publishing in the Philosophical Magazine in 1845. In the paper he was forthright in his rejection of the caloric reasoning of Carnot and Émile Clapeyron, a rejection partly theologically driven:
I conceive that this theory ... is opposed to the recognised principles of philosophy because it leads to the conclusion that vis viva may be destroyed by an improper disposition of the apparatus: Thus Mr Clapeyron draws the inference that 'the temperature of the fire being 1000 °C to 2000 °C higher than that of the boiler there is an enormous loss of vis viva in the passage of the heat from the furnace to the boiler.' Believing that the power to destroy belongs to the Creator alone I affirm ... that any theory which, when carried out, demands the annihilation of force, is necessarily erroneous.
Joule here adopts the language of vis viva (energy), possibly because Hodgkinson had read a review of Ewart's On the measure of moving force to the Literary and Philosophical Society in April 1844.
In June 1845, Joule read his paper On the Mechanical Equivalent of Heat to the British Association meeting in Cambridge. In this work, he reported his best-known experiment, involving the use of a falling weight, in which gravity does the mechanical work, to spin a paddle wheel in an insulated barrel of water which increased the temperature. He now estimated a mechanical equivalent of 819 foot-pounds force per British thermal unit (4.404 J/cal). He wrote a letter to the Philosophical Magazine, published in September 1845 describing his experiment.
In 1850, Joule published a refined measurement of 772.692 foot-pounds force per British thermal unit (4.155 J/cal), closer to twentieth century estimates.
Much of the initial resistance to Joule's work stemmed from its dependence upon extremely precise measurements. He claimed to be able to measure temperatures to within 1⁄200 of a degree Fahrenheit (3 mK). Such precision was certainly uncommon in contemporary experimental physics but his doubters may have neglected his experience in the art of brewing and his access to its practical technologies. He was also ably supported by scientific instrument-maker John Benjamin Dancer. Joule's experiments complemented the theoretical work of Rudolf Clausius, who is considered by some to be the coinventor of the energy concept.
Joule was proposing a kinetic theory of heat (he believed it to be a form of rotational, rather than translational, kinetic energy), and this required a conceptual leap: if heat was a form of molecular motion, why did the motion of the molecules not gradually die out? Joule's ideas required one to believe that the collisions of molecules were perfectly elastic. Importantly, the very existence of atoms and molecules was not widely accepted for another 50 years, though the essential work on the existence of molecules, atoms and electrons was underway throughout the 19th and early 20th centuries, from that of John Dalton through to Ernest Rutherford. A collection of Dalton’s works was published in 1893, 49 years after his death.